Holy Info! Thanks mpgriffiths. I'll see if I can comment/answer all your points.

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I think the info about Thomas burial, Ann burial, baptism & Hanna all have merit. Seems to line up with advice from Jefff. I'll explore those.
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I'll contact GRO for a copy of that will for Thomas (1820)
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Thanks for the Eliza info, I'll explore.
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I have that exact same 1841 Newert Census. The 1852 Canadian Census (http://data2.collectionscanada.ca/1851_pdf/e093/e002307321.pdf) shows all the children listed in the UK one (except William, I suspect passed on the trip or passed before traveling. They have an additional 4 Children in Canada. With this info and ages listed in 1952 I was trying to find immigration records for around 1842-44 but can't find records (see thread regarding Ancestry link)
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Glouc BDM is correct. I have records: Jane Elizabeth Smith, b. 1809 England, m. May 17 1830 in Newent, Gloucester, England, d. June 17, 1876 in Adamsville, Quebec, buried June 19, 1876 in Adamsville, Quebec.
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Ann Skynner/Skinner could be linked to shepway's 2nd point (Aug 12 at 8:28)
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Not sure about Richard. My records have only 1 Richard, son of Thomas Powles, b 1835
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I believe the family left England in 1842-44 so any census after that might not be relevant.
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Ann Skinner - My records of Anne Skinner, daughter of Thomas Powles place her 11 in 1852