From GFHS Marriage Index:
5 June 1824 Thomas HALE, Widower of Hundred of St Briavels married Anne BROWN of Hundred of St Briavels at Newland

This may be burial of first wife:
Date: 4 APR 1819
First Name: JANE
Surname: HALE
Age: 25
Burial Register: RUARDEAN 1813-1829
Place of Abode: COLFORD
City of Abode: -
Relationship: WIFE
Relationship To: THOMAS

From IGI:
6 May 1815 Thomas HALE married Jane WILLIAMS at Hope Mansell.

Mike